Acta Crystallographica Section E: Structure Reports Online - Volume 68, issue Pt 5

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Electronic ISSN
1600-5368

Abstract

In the mol­ecule of the title compound, C16H12ClF3N2O4S, the thia­diazine ring adopts a half-chair conformation. The dihedral angle between the benzene ring of the benzothia­diazine ring system and trifluoro­phenyl group is 15.02 (7)°. In the

Abstract

The racemic title compound, C9H11NO4·H2O, a tricyclic rearranged amino­norbornane dicarb­oxy­lic acid, is a conformationally rigid analogue of glutamic acid and exists as an ammonium-carboxyl­ate zwitterion, with the bridghead carb­oxy­lic acid group

Abstract

In the crystal structure of the racemic title compound, C22H25NO2, solved and refined against sychrotron diffraction data, the hy­droxy group and the carbonyl O atom participate in the formation of O—H⋯O hydrogen bonds between pairs of enanti­omers related by a cr

Abstract

In the title compound, C10H12N2OS2, the thione and S-methyl groups are syn. An intra­molecular bifurcated O—H⋯(S,N) hydrogen bond occurs.

Abstract

In the title complex, [Cu(C13H10ClN2O)Cl], the CuII ion is coordinated by one O atom and two N atoms of the tridentate Schiff base ligand and one chloride ion, forming a slightly distorted square-planar geometry. Weak Cu⋯Cl inter­actions [2.793 (5) Å] r

Abstract

In the title complex, cis-[PtCl4(C3H4N2)2], the PtIV ion lies on a twofold rotation axis and is coordinated in a slightly distorted octa­hedral geometry. The dihedral angle between the imidazole rings is 69.9 (2)°. In the cr

Abstract

In the title compound, {[Ca3Eu2(C7H3NO4)6(H2O)12]·10.5H2O}n, the EuIII ion is nine-coordinated by three tridentate pyridine-2,6-dicarboxyl­ate (PDA) ligands, forming a [

Abstract

The asymmetric unit of the title compound, (C6H14N)2[SbCl5], contains one cation and half of the anion on a special position (specifically, the SbIII ion and three chloride anions are situated on a mirror plane). In the [SbCl5]

Abstract

In the title compound, (C10H24N)[FeCl4], no classical hydrogen bonds are observed. The butyl­triethyl­ammonium cations inter­act with the tetra­hedral [FeCl4] anion through weak C—H⋯Cl inter­actions, forming a three-dimensional network.

Abstract

In the title compound, [Fe(C23H21O2)2(C5H8N2)2]·CH2Cl2, the Fe2+ cation is coordinated by the N atoms of two 3,5-dimethyl­pyrazole ligands and the carboxyl­ate O atoms from two