Tetra­kis(μ-3,4-dimethoxy­phenyl­acetato)bis­[(3,4-dimethoxy­phenyl­acetato)(1,10-phenanthroline)dysprosium(III)]

Liu, Jian-Feng a Xu, Xue-Dan a Li, Hua-Qiong a Zhao, Guo-Liang a * [a ] Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People’s Republic of China, and College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People’s Republic of China

Abstract

The title centrosymmetric dinuclear dysprosium(III) complex, [Dy 2(C 10H 11O 4) 6(C 12H 8N 2) 2] or [Dy( L) 3phen] 2, is comprised of six 3,4-dimethoxy­phenylacetate ( L) anions, two 1,10-phenanthroline (phen) mol­ecules and two Dy III ions. The Dy III atom is nine-coordinated by seven O atoms from five L ligands and two N atoms from the phen mol­ecules. The L ligands are coordinated to the Dy III ion in three coordination modes: chelating, bridging and bridging-tridentate. C—H⋯O hydrogen bonding interactions consolidate the crystal packing.

Related literature

For related structures, see: Li et al. (2006 , 2007 ). e-66-0m291-scheme1.jpg

Experimental

Crystal data

  • [Dy 2(C 10H 11O 4) 6(C 12H 8N 2) 2]

  • M r = 1856.54

  • Triclinic, e-66-0m291-efi1.jpg

  • a = 12.3287 (2) Å

  • b = 12.3843 (3) Å

  • c = 14.6667 (3) Å

  • α = 90.968 (1)°

  • β = 103.461 (1)°

  • γ = 115.523 (1)°

  • V = 1947.70 (7) Å 3

  • Z = 1

  • Mo Kα radiation

  • μ = 1.99 mm −1

  • T = 296 K

  • 0.43 × 0.19 × 0.07 mm

Data collection

  • Bruker APEXII CCD area-detector diffractometer

  • Absorption correction: multi-scan ( SADABS; Sheldrick, 1996 ) T min = 0.641, T max = 0.874

  • 26184 measured reflections

  • 6861 independent reflections

  • 5927 reflections with I > 2σ( I)

  • R int = 0.035

Refinement

  • R[ F 2 > 2σ( F 2)] = 0.028

  • wR( F 2) = 0.066

  • S = 1.03

  • 6861 reflections

  • 514 parameters

  • H-atom parameters constrained

  • Δρ max = 0.62 e Å −3

  • Δρ min = −0.42 e Å −3

Data collection: APEX2 (Bruker, 2006 ); cell refinement: SAINT (Bruker, 2006 ); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ); molecular graphics: SHELXTL (Sheldrick, 2008 ); software used to prepare material for publication: SHELXTL.

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810005143/pv2234sup1.cif

e-66-0m291-sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810005143/pv2234Isup2.hkl

e-66-0m291-Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Notes

[1] Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: PV2234).

Appendices

supplementary crystallographic information

Comment

The rare earth complexes with N/O-donors ligands such as 1,10-phenanthroline and carboxylic acid have received considerable attention for many years (Li et al., 2007; Li et al., 2006). The structure of the title compound, [Dy( L) 3phen] 2, (I), is a dinuclear dysprosium complex with Dy—DyA separation of 3.8887 (3) Å. The structure of the complex (Fig. 1) reveals that the molecule contains six 3,4-dimethoxyphenylacetic anions ( L) and two 1,10-phenanthroline (phen) molecules and two Dy III ions. The Dy III ion is nine-coordinated by two N atoms from one phen and seven O atoms from ( L) anions. The Dy—O bond distances range from 2.320 (2) to 2.522 (3) Å and the Dy—N bond distances are 2.536 (3) and 2.612 (3) Å, all of which are within the range of those of other nine-coordinated Dy III complexes with carboxylic donor ligands and 1,10-phenanthroline (Li et al., 2006). The ( L) ligands are coordinated to the Dy III ions in three different modes: chelating, bridging and bridging tridentate. Around each Dy III, there is one L ligand in chelating mode through two O atoms from the carboxyl group. Two symmetric L ligands bridge the two Dy centers though carboxyl O atoms. One L ligand is coordinated in a bidentate mode with Dy ion with O7 and O8 from carboxyl group and simultaneously bands to DyA ion with O8. In addition, there are no classical hydrogen bonds in the crystal structure, because good hydrogen bond donors are absent. The most significant intermolecular interactions are C—H···O hydrogen bonds (Table 1) and weak π···π aromatic interactions from phen molecules and aromatic rings of the L ligands. A packing plot is shown in Fig. 2.

Experimental

A mixture of 3,4-dimethoxyphenylacetic acid (0.5886 g, 3 mmol), Dy 2O 3 (0.1865 g, 0.5 mmol), 1,10-phenanthroline (0.1982 g, 1 mmol) and purified water (20 ml) was sealed in a 25 ml stainless steel reactor and kept at 433 K for 3 d. Then, the reactor was cooled to room temperature at a speed of 5 degrees per hour. Lots of pink single crystals were filtered out of the mixture at high field (80%).

Refinement

The H atoms bonded to C atoms were positioned geometrically and refined using a riding model with C—H distances: 0.96, and 0.93 Å for aliphatic and aromatic, respectively, and U iso(H) = 1.5 U eq( C-methoxyl) or 1.2 U eq(the rest of the parent atoms).

Figures

Fig. 1.

The molecular structure of the title complex. Displacement ellipsoids are drawn at the 30% probability level. The letter A in the atomic labels represents the symmetry operation: -x, -y+1, -z+1.

The molecular structure of the title complex. Displacement ellipsoids are drawn at the 30% probability level. The letter A in the atomic labels represents the symmetry operation: -x, -y+1, -z+1.
Fig. 2.

The packing plot of the title complex showing intermolecular interactions.

The packing plot of the title complex showing intermolecular interactions.

Crystal data

[Dy 2(C 10H 11O 4) 6(C 12H 8N 2) 2] Z = 1
M r = 1856.54 F(000) = 938
Triclinic, P1 D x = 1.583 Mg m 3
Hall symbol: -p 1 Mo Kα radiation, λ = 0.71073 Å
a = 12.3287 (2) Å Cell parameters from 9399 reflections
b = 12.3843 (3) Å θ = 1.8–25.0°
c = 14.6667 (3) Å µ = 1.99 mm 1
α = 90.968 (1)° T = 296 K
β = 103.461 (1)° Plate, pink
γ = 115.523 (1)° 0.43 × 0.19 × 0.07 mm
V = 1947.70 (7) Å 3

Data collection

Bruker APEXII CCD area-detector diffractometer 6861 independent reflections
Radiation source: fine-focus sealed tube 5927 reflections with I > 2σ( I)
graphite R int = 0.035
phi and ω scans θ max = 25.0°, θ min = 1.8°
Absorption correction: multi-scan ( SADABS; Sheldrick, 1996) h = −13→14
T min = 0.641, T max = 0.874 k = −14→14
26184 measured reflections l = −17→17

Refinement

Refinement on F 2 Primary atom site location: structure-invariant direct methods
Least-squares matrix: full Secondary atom site location: difference Fourier map
R[ F 2 > 2σ( F 2)] = 0.028 Hydrogen site location: inferred from neighbouring sites
wR( F 2) = 0.066 H-atom parameters constrained
S = 1.03 w = 1/[σ 2( F o 2) + (0.0353 P) 2 + 0.1683 P] where P = ( F o 2 + 2 F c 2)/3
6861 reflections (Δ/σ) max = 0.003
514 parameters Δρ max = 0.62 e Å 3
0 restraints Δρ min = −0.41 e Å 3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F 2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F 2, conventional R-factors R are based on F, with F set to zero for negative F 2. The threshold expression of F 2 > σ( F 2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F 2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å 2)

x y z U iso*/ U eq
Dy 0.177981 (13) 0.606337 (14) 0.531660 (10) 0.04130 (7)
N1 0.3869 (2) 0.6453 (2) 0.5047 (2) 0.0503 (7)
O1 0.2349 (3) 1.0157 (3) 0.06745 (19) 0.0829 (9)
C1 0.3116 (5) 1.0035 (5) 0.0144 (3) 0.1012 (17)
H1A 0.2851 1.0170 −0.0494 0.152*
H1B 0.3055 0.9235 0.0144 0.152*
H1C 0.3965 1.0616 0.0422 0.152*
N2 0.3613 (2) 0.6607 (2) 0.68308 (19) 0.0459 (7)
C2 0.2595 (3) 0.9987 (3) 0.1610 (2) 0.0562 (9)
O2 0.1032 (3) 1.0566 (3) 0.1614 (2) 0.0796 (8)
O3 0.2631 (2) 0.8206 (2) 0.56316 (15) 0.0566 (6)
C3 0.3471 (4) 0.9643 (4) 0.2054 (3) 0.0642 (10)
H3A 0.3941 0.9475 0.1713 0.077*
O4 0.2246 (2) 0.7496 (2) 0.41548 (15) 0.0475 (5)
C4 0.3663 (4) 0.9542 (4) 0.3007 (3) 0.0642 (10)
H4A 0.4269 0.9313 0.3305 0.077*
O5 0.3890 (2) 0.2633 (2) 0.86802 (17) 0.0673 (7)
C5 0.2964 (3) 0.9778 (3) 0.3524 (2) 0.0524 (9)
O6 0.3680 (2) 0.0570 (2) 0.80505 (16) 0.0532 (6)
C6 0.2069 (3) 1.0102 (3) 0.3066 (2) 0.0545 (9)
H6A 0.1586 1.0251 0.3404 0.065*
O7 0.2059 (2) 0.4291 (2) 0.58527 (16) 0.0494 (6)
C7 0.1870 (3) 1.0212 (3) 0.2118 (3) 0.0566 (9)
O8 0.01314 (19) 0.4012 (2) 0.54405 (14) 0.0460 (5)
C8 0.0165 (4) 1.0668 (4) 0.2060 (4) 0.0875 (14)
H8A −0.0363 1.0931 0.1633 0.131*
H8B 0.0609 1.1246 0.2621 0.131*
H8C −0.0335 0.9897 0.2226 0.131*
O9 −0.1582 (3) 0.6792 (3) −0.0064 (2) 0.0863 (9)
C9 0.3152 (4) 0.9648 (3) 0.4557 (2) 0.0599 (10)
H9A 0.2761 1.0058 0.4827 0.072*
H9B 0.4039 1.0056 0.4865 0.072*
C10 0.2645 (3) 0.8366 (3) 0.4783 (2) 0.0452 (8)
O10 −0.2506 (3) 0.4530 (3) −0.0641 (2) 0.0989 (11)
O11 0.1139 (2) 0.4816 (2) 0.38781 (15) 0.0482 (6)
C11 0.4211 (4) 0.3853 (4) 0.8958 (3) 0.0858 (14)
H11A 0.4817 0.4130 0.9562 0.129*
H11B 0.3479 0.3923 0.9005 0.129*
H11C 0.4553 0.4335 0.8497 0.129*
C12 0.3019 (3) 0.2086 (3) 0.7835 (2) 0.0449 (8)
O12 −0.0940 (2) 0.3744 (2) 0.34464 (14) 0.0528 (6)
C13 0.2243 (3) 0.2534 (3) 0.7331 (2) 0.0457 (8)
H13A 0.2298 0.3261 0.7571 0.055*
C14 0.1386 (3) 0.1928 (3) 0.6477 (2) 0.0464 (8)
C15 0.1379 (3) 0.0886 (3) 0.6125 (2) 0.0589 (10)
H15A 0.0858 0.0494 0.5531 0.071*
C16 0.2124 (3) 0.0407 (3) 0.6630 (2) 0.0544 (9)
H16A 0.2074 −0.0315 0.6383 0.065*
C17 0.2931 (3) 0.0986 (3) 0.7490 (2) 0.0422 (7)
C18 0.3356 (4) −0.0674 (3) 0.7839 (3) 0.0643 (10)
H18A 0.3933 −0.0875 0.8275 0.096*
H18B 0.3389 −0.0830 0.7205 0.096*
H18C 0.2527 −0.1157 0.7894 0.096*
C19 0.0456 (3) 0.2354 (3) 0.5983 (3) 0.0555 (9)
H19A −0.0037 0.1815 0.5397 0.067*
H19B −0.0105 0.2259 0.6374 0.067*
C20 0.0937 (3) 0.3622 (3) 0.5749 (2) 0.0405 (7)
C21 −0.1059 (5) 0.8059 (4) 0.0225 (4) 0.1040 (18)
H21A −0.1436 0.8415 −0.0243 0.156*
H21B −0.0176 0.8419 0.0294 0.156*
H21C −0.1212 0.8195 0.0819 0.156*
C22 −0.1141 (4) 0.6150 (4) 0.0525 (3) 0.0619 (10)
C23 −0.0238 (4) 0.6649 (4) 0.1381 (3) 0.0674 (11)
H23A 0.0099 0.7471 0.1584 0.081*
C24 0.0166 (4) 0.5926 (4) 0.1936 (3) 0.0626 (10)
H24A 0.0772 0.6267 0.2508 0.075*
C25 −0.0327 (3) 0.4709 (3) 0.1643 (2) 0.0505 (9)
C26 −0.1208 (3) 0.4213 (4) 0.0791 (3) 0.0609 (10)
H26A −0.1533 0.3393 0.0589 0.073*
C27 −0.1623 (4) 0.4931 (4) 0.0224 (3) 0.0651 (10)
C28 −0.2940 (5) 0.3346 (5) −0.1046 (4) 0.1117 (19)
H28A −0.3547 0.3192 −0.1639 0.168*
H28B −0.3318 0.2802 −0.0628 0.168*
H28C −0.2257 0.3227 −0.1149 0.168*
C29 0.0135 (3) 0.3945 (3) 0.2268 (2) 0.0553 (9)
H29A 0.0978 0.4133 0.2250 0.066*
H29B −0.0391 0.3097 0.2030 0.066*
C30 0.0115 (3) 0.4185 (3) 0.3286 (2) 0.0473 (8)
C31 0.4017 (4) 0.6446 (3) 0.4185 (3) 0.0638 (10)
H31A 0.3370 0.6388 0.3679 0.077*
C32 0.5118 (4) 0.6525 (4) 0.4003 (3) 0.0741 (12)
H32A 0.5205 0.6538 0.3390 0.089*
C33 0.6049 (4) 0.6581 (3) 0.4738 (4) 0.0760 (13)
H33A 0.6773 0.6611 0.4626 0.091*
C34 0.5935 (3) 0.6595 (3) 0.5658 (3) 0.0620 (11)
C35 0.6869 (3) 0.6620 (4) 0.6466 (4) 0.0800 (14)
H35A 0.7584 0.6600 0.6378 0.096*
C36 0.6733 (4) 0.6672 (4) 0.7337 (4) 0.0773 (13)
H36A 0.7353 0.6686 0.7846 0.093*
C37 0.5655 (3) 0.6707 (3) 0.7505 (3) 0.0567 (10)
C38 0.5496 (4) 0.6802 (3) 0.8402 (3) 0.0664 (11)
H38A 0.6120 0.6869 0.8931 0.080*
C39 0.4428 (4) 0.6796 (3) 0.8510 (3) 0.0630 (10)
H39A 0.4315 0.6863 0.9110 0.076*
C40 0.3506 (3) 0.6686 (3) 0.7704 (2) 0.0537 (9)
H40A 0.2772 0.6666 0.7785 0.064*
C41 0.4684 (3) 0.6621 (3) 0.6729 (3) 0.0457 (8)
C42 0.4820 (3) 0.6547 (3) 0.5790 (3) 0.0508 (9)

Atomic displacement parameters (Å 2)

U 11 U 22 U 33 U 12 U 13 U 23
Dy 0.04383 (10) 0.06268 (12) 0.04051 (10) 0.03999 (8) 0.01945 (7) 0.02237 (7)
N1 0.0516 (17) 0.0574 (18) 0.0621 (18) 0.0350 (14) 0.0295 (15) 0.0213 (14)
O1 0.094 (2) 0.120 (3) 0.0521 (16) 0.0582 (19) 0.0282 (15) 0.0339 (16)
C1 0.144 (5) 0.128 (4) 0.059 (3) 0.074 (4) 0.047 (3) 0.027 (3)
N2 0.0432 (15) 0.0532 (17) 0.0548 (17) 0.0325 (13) 0.0146 (13) 0.0193 (13)
C2 0.062 (2) 0.063 (2) 0.044 (2) 0.0268 (19) 0.0177 (18) 0.0211 (17)
O2 0.0745 (18) 0.105 (2) 0.081 (2) 0.0553 (17) 0.0263 (16) 0.0420 (17)
O3 0.0806 (17) 0.0676 (16) 0.0394 (13) 0.0464 (14) 0.0205 (12) 0.0201 (11)
C3 0.071 (3) 0.082 (3) 0.058 (2) 0.044 (2) 0.030 (2) 0.021 (2)
O4 0.0591 (14) 0.0579 (14) 0.0413 (12) 0.0367 (12) 0.0198 (11) 0.0157 (11)
C4 0.069 (2) 0.077 (3) 0.061 (2) 0.044 (2) 0.020 (2) 0.026 (2)
O5 0.0830 (18) 0.0541 (15) 0.0560 (15) 0.0393 (14) −0.0142 (13) 0.0010 (12)
C5 0.061 (2) 0.047 (2) 0.051 (2) 0.0238 (17) 0.0186 (18) 0.0141 (16)
O6 0.0590 (14) 0.0567 (15) 0.0538 (14) 0.0407 (12) 0.0028 (11) 0.0115 (11)
C6 0.064 (2) 0.053 (2) 0.056 (2) 0.0290 (18) 0.0279 (18) 0.0168 (17)
O7 0.0439 (13) 0.0618 (15) 0.0610 (15) 0.0380 (12) 0.0175 (11) 0.0249 (12)
C7 0.057 (2) 0.055 (2) 0.062 (2) 0.0280 (18) 0.0192 (19) 0.0238 (18)
O8 0.0490 (13) 0.0713 (15) 0.0457 (13) 0.0476 (12) 0.0207 (10) 0.0274 (11)
C8 0.070 (3) 0.091 (3) 0.118 (4) 0.049 (3) 0.028 (3) 0.030 (3)
O9 0.102 (2) 0.089 (2) 0.0710 (19) 0.0555 (19) 0.0011 (16) 0.0217 (16)
C9 0.075 (3) 0.055 (2) 0.048 (2) 0.0282 (19) 0.0167 (19) 0.0128 (17)
C10 0.0458 (19) 0.064 (2) 0.0439 (19) 0.0392 (17) 0.0139 (15) 0.0185 (17)
O10 0.097 (2) 0.094 (2) 0.083 (2) 0.0435 (19) −0.0172 (18) −0.0099 (19)
O11 0.0475 (13) 0.0701 (16) 0.0469 (13) 0.0390 (12) 0.0223 (11) 0.0186 (12)
C11 0.104 (4) 0.055 (3) 0.082 (3) 0.042 (2) −0.015 (3) −0.009 (2)
C12 0.0491 (19) 0.0464 (19) 0.0419 (18) 0.0250 (16) 0.0090 (15) 0.0118 (15)
O12 0.0482 (13) 0.0853 (17) 0.0423 (13) 0.0424 (13) 0.0176 (11) 0.0165 (12)
C13 0.055 (2) 0.0414 (18) 0.051 (2) 0.0293 (16) 0.0150 (16) 0.0160 (15)
C14 0.0441 (18) 0.050 (2) 0.052 (2) 0.0282 (16) 0.0104 (16) 0.0193 (16)
C15 0.064 (2) 0.064 (2) 0.049 (2) 0.040 (2) −0.0061 (17) −0.0015 (18)
C16 0.064 (2) 0.060 (2) 0.050 (2) 0.0435 (19) 0.0037 (17) 0.0023 (17)
C17 0.0449 (18) 0.0499 (19) 0.0435 (18) 0.0303 (16) 0.0138 (15) 0.0157 (15)
C18 0.086 (3) 0.062 (2) 0.063 (2) 0.053 (2) 0.011 (2) 0.0158 (19)
C19 0.0443 (19) 0.057 (2) 0.070 (2) 0.0320 (17) 0.0051 (17) 0.0160 (18)
C20 0.0462 (19) 0.060 (2) 0.0358 (17) 0.0395 (17) 0.0145 (14) 0.0159 (15)
C21 0.128 (4) 0.084 (4) 0.100 (4) 0.055 (3) 0.013 (3) 0.043 (3)
C22 0.069 (2) 0.075 (3) 0.046 (2) 0.038 (2) 0.0133 (19) 0.018 (2)
C23 0.080 (3) 0.065 (3) 0.054 (2) 0.034 (2) 0.010 (2) 0.014 (2)
C24 0.069 (2) 0.070 (3) 0.047 (2) 0.033 (2) 0.0083 (18) 0.0149 (19)
C25 0.054 (2) 0.072 (3) 0.0380 (18) 0.0337 (19) 0.0226 (16) 0.0158 (17)
C26 0.063 (2) 0.069 (3) 0.055 (2) 0.032 (2) 0.0169 (19) 0.0088 (19)
C27 0.061 (2) 0.083 (3) 0.056 (2) 0.038 (2) 0.0115 (19) 0.016 (2)
C28 0.097 (4) 0.124 (5) 0.082 (4) 0.038 (3) −0.007 (3) −0.026 (3)
C29 0.064 (2) 0.077 (3) 0.048 (2) 0.047 (2) 0.0249 (17) 0.0145 (18)
C30 0.059 (2) 0.068 (2) 0.0456 (19) 0.0481 (19) 0.0263 (18) 0.0253 (17)
C31 0.068 (2) 0.076 (3) 0.074 (3) 0.045 (2) 0.041 (2) 0.025 (2)
C32 0.076 (3) 0.074 (3) 0.099 (3) 0.040 (2) 0.059 (3) 0.017 (2)
C33 0.051 (2) 0.057 (2) 0.137 (4) 0.028 (2) 0.050 (3) 0.007 (3)
C34 0.042 (2) 0.047 (2) 0.106 (3) 0.0225 (17) 0.033 (2) 0.007 (2)
C35 0.0288 (19) 0.060 (3) 0.149 (5) 0.0246 (18) 0.012 (2) −0.007 (3)
C36 0.043 (2) 0.064 (3) 0.118 (4) 0.029 (2) 0.000 (2) −0.004 (3)
C37 0.0387 (19) 0.042 (2) 0.085 (3) 0.0208 (16) 0.0018 (19) 0.0102 (19)
C38 0.057 (2) 0.054 (2) 0.076 (3) 0.0277 (19) −0.010 (2) 0.015 (2)
C39 0.066 (2) 0.066 (3) 0.056 (2) 0.036 (2) 0.0031 (19) 0.0160 (19)
C40 0.055 (2) 0.064 (2) 0.054 (2) 0.0370 (18) 0.0116 (17) 0.0190 (18)
C41 0.0385 (17) 0.0358 (17) 0.067 (2) 0.0211 (14) 0.0123 (16) 0.0159 (16)
C42 0.0382 (18) 0.0408 (19) 0.085 (3) 0.0241 (15) 0.0231 (18) 0.0175 (18)

Geometric parameters (Å, °)

Dy—O8 i 2.320 (2) C12—C17 1.395 (4)
Dy—O12 i 2.343 (2) O12—C30 1.257 (4)
Dy—O11 2.350 (2) O12—Dy i 2.343 (2)
Dy—O3 2.385 (2) C13—C14 1.385 (4)
Dy—O4 2.462 (2) C13—H13A 0.9300
Dy—O7 2.478 (2) C14—C15 1.377 (5)
Dy—O8 2.521 (2) C14—C19 1.505 (4)
Dy—N1 2.536 (3) C15—C16 1.383 (4)
Dy—N2 2.607 (3) C15—H15A 0.9300
Dy—C10 2.780 (3) C16—C17 1.366 (4)
Dy—C20 2.879 (3) C16—H16A 0.9300
Dy—Dy i 3.8882 (3) C18—H18A 0.9600
N1—C31 1.320 (4) C18—H18B 0.9600
N1—C42 1.363 (4) C18—H18C 0.9600
O1—C2 1.374 (4) C19—C20 1.499 (5)
O1—C1 1.408 (5) C19—H19A 0.9700
C1—H1A 0.9600 C19—H19B 0.9700
C1—H1B 0.9600 C21—H21A 0.9600
C1—H1C 0.9600 C21—H21B 0.9600
N2—C40 1.324 (4) C21—H21C 0.9600
N2—C41 1.355 (4) C22—C27 1.382 (5)
C2—C3 1.360 (5) C22—C23 1.388 (5)
C2—C7 1.397 (5) C23—C24 1.390 (5)
O2—C7 1.361 (4) C23—H23A 0.9300
O2—C8 1.423 (5) C24—C25 1.375 (5)
O3—C10 1.267 (4) C24—H24A 0.9300
C3—C4 1.379 (5) C25—C26 1.374 (5)
C3—H3A 0.9300 C25—C29 1.519 (5)
O4—C10 1.245 (4) C26—C27 1.401 (5)
C4—C5 1.385 (5) C26—H26A 0.9300
C4—H4A 0.9300 C28—H28A 0.9600
O5—C12 1.369 (4) C28—H28B 0.9600
O5—C11 1.413 (4) C28—H28C 0.9600
C5—C6 1.369 (5) C29—C30 1.525 (4)
C5—C9 1.500 (5) C29—H29A 0.9700
O6—C17 1.366 (4) C29—H29B 0.9700
O6—C18 1.423 (4) C31—C32 1.406 (5)
C6—C7 1.374 (5) C31—H31A 0.9300
C6—H6A 0.9300 C32—C33 1.355 (6)
O7—C20 1.238 (4) C32—H32A 0.9300
O8—C20 1.279 (3) C33—C34 1.389 (6)
O8—Dy i 2.320 (2) C33—H33A 0.9300
C8—H8A 0.9600 C34—C42 1.408 (4)
C8—H8B 0.9600 C34—C35 1.436 (6)
C8—H8C 0.9600 C35—C36 1.331 (6)
O9—C22 1.360 (4) C35—H35A 0.9300
O9—C21 1.427 (5) C36—C37 1.424 (5)
C9—C10 1.509 (5) C36—H36A 0.9300
C9—H9A 0.9700 C37—C38 1.385 (5)
C9—H9B 0.9700 C37—C41 1.411 (5)
O10—C27 1.383 (5) C38—C39 1.359 (5)
O10—C28 1.391 (6) C38—H38A 0.9300
O11—C30 1.255 (4) C39—C40 1.394 (5)
C11—H11A 0.9600 C39—H39A 0.9300
C11—H11B 0.9600 C40—H40A 0.9300
C11—H11C 0.9600 C41—C42 1.432 (5)
C12—C13 1.383 (4)
O8 i—Dy—O12 i 75.76 (7) O3—C10—Dy 58.83 (17)
O8 i—Dy—O11 75.61 (8) C9—C10—Dy 176.4 (2)
O12 i—Dy—O11 138.17 (8) C27—O10—C28 118.5 (4)
O8 i—Dy—O3 89.20 (8) C30—O11—Dy 135.4 (2)
O12 i—Dy—O3 79.24 (8) O5—C11—H11A 109.5
O11—Dy—O3 129.88 (7) O5—C11—H11B 109.5
O8 i—Dy—O4 75.39 (7) H11A—C11—H11B 109.5
O12 i—Dy—O4 124.07 (8) O5—C11—H11C 109.5
O11—Dy—O4 76.27 (7) H11A—C11—H11C 109.5
O3—Dy—O4 53.63 (7) H11B—C11—H11C 109.5
O8 i—Dy—O7 124.00 (7) O5—C12—C13 125.1 (3)
O12 i—Dy—O7 93.54 (8) O5—C12—C17 115.2 (3)
O11—Dy—O7 78.13 (8) C13—C12—C17 119.7 (3)
O3—Dy—O7 143.46 (8) C30—O12—Dy i 137.0 (2)
O4—Dy—O7 142.07 (7) C12—C13—C14 121.6 (3)
O8 i—Dy—O8 73.21 (8) C12—C13—H13A 119.2
O12 i—Dy—O8 71.42 (8) C14—C13—H13A 119.2
O11—Dy—O8 71.51 (7) C15—C14—C13 117.2 (3)
O3—Dy—O8 148.60 (8) C15—C14—C19 121.4 (3)
O4—Dy—O8 139.39 (7) C13—C14—C19 121.3 (3)
O7—Dy—O8 51.68 (7) C14—C15—C16 121.9 (3)
O8 i—Dy—N1 141.81 (8) C14—C15—H15A 119.1
O12 i—Dy—N1 139.40 (9) C16—C15—H15A 119.1
O11—Dy—N1 79.07 (8) C17—C16—C15 120.4 (3)
O3—Dy—N1 85.52 (9) C17—C16—H16A 119.8
O4—Dy—N1 71.12 (8) C15—C16—H16A 119.8
O7—Dy—N1 76.92 (8) C16—C17—O6 124.6 (3)
O8—Dy—N1 124.31 (8) C16—C17—C12 118.9 (3)
O8 i—Dy—N2 150.45 (8) O6—C17—C12 116.4 (3)
O12 i—Dy—N2 76.08 (8) O6—C18—H18A 109.5
O11—Dy—N2 133.00 (8) O6—C18—H18B 109.5
O3—Dy—N2 76.91 (8) H18A—C18—H18B 109.5
O4—Dy—N2 114.21 (8) O6—C18—H18C 109.5
O7—Dy—N2 66.60 (8) H18A—C18—H18C 109.5
O8—Dy—N2 105.80 (7) H18B—C18—H18C 109.5
N1—Dy—N2 63.83 (9) C20—C19—C14 118.3 (3)
O8 i—Dy—C10 81.72 (8) C20—C19—H19A 107.7
O12 i—Dy—C10 102.46 (9) C14—C19—H19A 107.7
O11—Dy—C10 102.86 (9) C20—C19—H19B 107.7
O3—Dy—C10 27.04 (8) C14—C19—H19B 107.7
O4—Dy—C10 26.60 (8) H19A—C19—H19B 107.1
O7—Dy—C10 152.75 (8) O7—C20—O8 119.9 (3)
O8—Dy—C10 154.93 (8) O7—C20—C19 123.0 (3)
N1—Dy—C10 76.57 (9) O8—C20—C19 117.1 (3)
N2—Dy—C10 95.80 (9) O7—C20—Dy 58.91 (17)
O8 i—Dy—C20 99.15 (8) O8—C20—Dy 61.01 (16)
O12 i—Dy—C20 81.93 (8) C19—C20—Dy 177.8 (2)
O11—Dy—C20 73.28 (8) O9—C21—H21A 109.5
O3—Dy—C20 156.83 (8) O9—C21—H21B 109.5
O4—Dy—C20 149.44 (8) H21A—C21—H21B 109.5
O7—Dy—C20 25.34 (7) O9—C21—H21C 109.5
O8—Dy—C20 26.35 (7) H21A—C21—H21C 109.5
N1—Dy—C20 100.38 (9) H21B—C21—H21C 109.5
N2—Dy—C20 85.57 (8) O9—C22—C27 116.4 (3)
C10—Dy—C20 175.59 (9) O9—C22—C23 124.1 (4)
O8 i—Dy—Dy i 38.37 (5) C27—C22—C23 119.4 (4)
O12 i—Dy—Dy i 69.31 (5) C22—C23—C24 120.3 (4)
O11—Dy—Dy i 69.27 (5) C22—C23—H23A 119.9
O3—Dy—Dy i 123.04 (6) C24—C23—H23A 119.9
O4—Dy—Dy i 109.98 (5) C25—C24—C23 120.4 (3)
O7—Dy—Dy i 86.08 (5) C25—C24—H24A 119.8
O8—Dy—Dy i 34.84 (5) C23—C24—H24A 119.8
N1—Dy—Dy i 146.56 (7) C26—C25—C24 119.6 (4)
N2—Dy—Dy i 134.08 (6) C26—C25—C29 121.4 (3)
C10—Dy—Dy i 120.10 (6) C24—C25—C29 119.0 (3)
C20—Dy—Dy i 60.91 (6) C25—C26—C27 120.6 (4)
C31—N1—C42 118.8 (3) C25—C26—H26A 119.7
C31—N1—Dy 121.0 (2) C27—C26—H26A 119.7
C42—N1—Dy 119.9 (2) C22—C27—O10 114.7 (4)
C2—O1—C1 117.3 (3) C22—C27—C26 119.7 (4)
O1—C1—H1A 109.5 O10—C27—C26 125.6 (4)
O1—C1—H1B 109.5 O10—C28—H28A 109.5
H1A—C1—H1B 109.5 O10—C28—H28B 109.5
O1—C1—H1C 109.5 H28A—C28—H28B 109.5
H1A—C1—H1C 109.5 O10—C28—H28C 109.5
H1B—C1—H1C 109.5 H28A—C28—H28C 109.5
C40—N2—C41 117.1 (3) H28B—C28—H28C 109.5
C40—N2—Dy 124.0 (2) C25—C29—C30 110.7 (3)
C41—N2—Dy 118.0 (2) C25—C29—H29A 109.5
C3—C2—O1 125.5 (4) C30—C29—H29A 109.5
C3—C2—C7 119.7 (3) C25—C29—H29B 109.5
O1—C2—C7 114.8 (3) C30—C29—H29B 109.5
C7—O2—C8 117.9 (3) H29A—C29—H29B 108.1
C10—O3—Dy 94.1 (2) O11—C30—O12 126.1 (3)
C2—C3—C4 120.2 (4) O11—C30—C29 117.6 (3)
C2—C3—H3A 119.9 O12—C30—C29 116.2 (3)
C4—C3—H3A 119.9 N1—C31—C32 122.4 (4)
C10—O4—Dy 91.09 (19) N1—C31—H31A 118.8
C3—C4—C5 120.8 (4) C32—C31—H31A 118.8
C3—C4—H4A 119.6 C33—C32—C31 118.8 (4)
C5—C4—H4A 119.6 C33—C32—H32A 120.6
C12—O5—C11 117.3 (3) C31—C32—H32A 120.6
C6—C5—C4 118.4 (3) C32—C33—C34 120.7 (4)
C6—C5—C9 120.5 (3) C32—C33—H33A 119.6
C4—C5—C9 121.1 (4) C34—C33—H33A 119.6
C17—O6—C18 116.2 (3) C33—C34—C42 117.3 (4)
C5—C6—C7 121.5 (3) C33—C34—C35 123.6 (4)
C5—C6—H6A 119.2 C42—C34—C35 119.0 (4)
C7—C6—H6A 119.2 C36—C35—C34 121.3 (4)
C20—O7—Dy 95.75 (19) C36—C35—H35A 119.4
O2—C7—C6 125.4 (4) C34—C35—H35A 119.4
O2—C7—C2 115.2 (3) C35—C36—C37 121.3 (4)
C6—C7—C2 119.3 (4) C35—C36—H36A 119.3
C20—O8—Dy i 158.0 (2) C37—C36—H36A 119.3
C20—O8—Dy 92.64 (19) C38—C37—C41 117.5 (3)
Dy i—O8—Dy 106.79 (8) C38—C37—C36 123.1 (4)
O2—C8—H8A 109.5 C41—C37—C36 119.4 (4)
O2—C8—H8B 109.5 C39—C38—C37 120.1 (3)
H8A—C8—H8B 109.5 C39—C38—H38A 120.0
O2—C8—H8C 109.5 C37—C38—H38A 120.0
H8A—C8—H8C 109.5 C38—C39—C40 118.7 (4)
H8B—C8—H8C 109.5 C38—C39—H39A 120.7
C22—O9—C21 116.9 (3) C40—C39—H39A 120.7
C5—C9—C10 115.4 (3) N2—C40—C39 123.9 (4)
C5—C9—H9A 108.4 N2—C40—H40A 118.0
C10—C9—H9A 108.4 C39—C40—H40A 118.0
C5—C9—H9B 108.4 N2—C41—C37 122.8 (3)
C10—C9—H9B 108.4 N2—C41—C42 117.8 (3)
H9A—C9—H9B 107.5 C37—C41—C42 119.4 (3)
O4—C10—O3 121.1 (3) N1—C42—C34 121.9 (4)
O4—C10—C9 121.1 (3) N1—C42—C41 118.7 (3)
O3—C10—C9 117.8 (3) C34—C42—C41 119.4 (3)
O4—C10—Dy 62.31 (17)
O8 i—Dy—N1—C31 −15.6 (3) O8 i—Dy—C10—O3 104.72 (19)
O12 i—Dy—N1—C31 −166.3 (2) O12 i—Dy—C10—O3 31.4 (2)
O11—Dy—N1—C31 33.5 (3) O11—Dy—C10—O3 177.81 (18)
O3—Dy—N1—C31 −98.5 (3) O4—Dy—C10—O3 178.5 (3)
O4—Dy—N1—C31 −45.5 (3) O7—Dy—C10—O3 −93.2 (3)
O7—Dy—N1—C31 113.7 (3) O8—Dy—C10—O3 104.1 (2)
O8—Dy—N1—C31 92.0 (3) N1—Dy—C10—O3 −106.9 (2)
N2—Dy—N1—C31 −176.1 (3) N2—Dy—C10—O3 −45.61 (19)
C10—Dy—N1—C31 −72.7 (3) Dy i—Dy—C10—O3 104.51 (18)
C20—Dy—N1—C31 104.1 (3) O8 i—Dy—O11—C30 −22.2 (3)
Dy i—Dy—N1—C31 52.4 (3) O12 i—Dy—O11—C30 25.9 (3)
O8 i—Dy—N1—C42 171.3 (2) O3—Dy—O11—C30 −98.7 (3)
O12 i—Dy—N1—C42 20.6 (3) O4—Dy—O11—C30 −100.3 (3)
O11—Dy—N1—C42 −139.6 (2) O7—Dy—O11—C30 107.9 (3)
O3—Dy—N1—C42 88.3 (2) O8—Dy—O11—C30 54.6 (3)
O4—Dy—N1—C42 141.3 (3) N1—Dy—O11—C30 −173.3 (3)
O7—Dy—N1—C42 −59.4 (2) N2—Dy—O11—C30 149.2 (3)
O8—Dy—N1—C42 −81.1 (3) C10—Dy—O11—C30 −100.0 (3)
N2—Dy—N1—C42 10.7 (2) C20—Dy—O11—C30 82.2 (3)
C10—Dy—N1—C42 114.2 (3) Dy i—Dy—O11—C30 17.6 (3)
C20—Dy—N1—C42 −69.1 (2) C11—O5—C12—C13 −14.3 (5)
Dy i—Dy—N1—C42 −120.8 (2) C11—O5—C12—C17 166.5 (3)
O8 i—Dy—N2—C40 24.7 (3) O5—C12—C13—C14 179.8 (3)
O12 i—Dy—N2—C40 6.7 (3) C17—C12—C13—C14 −1.0 (5)
O11—Dy—N2—C40 −138.2 (2) C12—C13—C14—C15 −3.1 (5)
O3—Dy—N2—C40 88.7 (3) C12—C13—C14—C19 173.6 (3)
O4—Dy—N2—C40 128.1 (3) C13—C14—C15—C16 4.9 (5)
O7—Dy—N2—C40 −93.5 (3) C19—C14—C15—C16 −171.9 (3)
O8—Dy—N2—C40 −59.0 (3) C14—C15—C16—C17 −2.4 (6)
N1—Dy—N2—C40 −179.9 (3) C15—C16—C17—O6 178.3 (3)
C10—Dy—N2—C40 108.1 (3) C15—C16—C17—C12 −1.9 (5)
C20—Dy—N2—C40 −76.1 (3) C18—O6—C17—C16 −17.1 (5)
Dy i—Dy—N2—C40 −35.0 (3) C18—O6—C17—C12 163.1 (3)
O8 i—Dy—N2—C41 −166.39 (19) O5—C12—C17—C16 −177.2 (3)
O12 i—Dy—N2—C41 175.6 (2) C13—C12—C17—C16 3.6 (5)
O11—Dy—N2—C41 30.7 (3) O5—C12—C17—O6 2.7 (4)
O3—Dy—N2—C41 −102.4 (2) C13—C12—C17—O6 −176.6 (3)
O4—Dy—N2—C41 −63.0 (2) C15—C14—C19—C20 −127.0 (4)
O7—Dy—N2—C41 75.4 (2) C13—C14—C19—C20 56.4 (5)
O8—Dy—N2—C41 109.9 (2) Dy—O7—C20—O8 0.4 (3)
N1—Dy—N2—C41 −11.0 (2) Dy—O7—C20—C19 −178.8 (3)
C10—Dy—N2—C41 −83.0 (2) Dy i—O8—C20—O7 152.0 (4)
C20—Dy—N2—C41 92.8 (2) Dy—O8—C20—O7 −0.4 (3)
Dy i—Dy—N2—C41 133.93 (19) Dy i—O8—C20—C19 −28.7 (7)
C1—O1—C2—C3 −4.0 (6) Dy—O8—C20—C19 178.8 (3)
C1—O1—C2—C7 175.2 (4) Dy i—O8—C20—Dy 152.4 (5)
O8 i—Dy—O3—C10 −73.18 (19) C14—C19—C20—O7 7.9 (5)
O12 i—Dy—O3—C10 −148.8 (2) C14—C19—C20—O8 −171.3 (3)
O11—Dy—O3—C10 −2.8 (2) O8 i—Dy—C20—O7 169.48 (18)
O4—Dy—O3—C10 −0.82 (17) O12 i—Dy—C20—O7 −116.45 (19)
O7—Dy—O3—C10 129.84 (19) O11—Dy—C20—O7 97.62 (19)
O8—Dy—O3—C10 −127.92 (19) O3—Dy—C20—O7 −80.6 (3)
N1—Dy—O3—C10 68.97 (19) O4—Dy—C20—O7 92.8 (2)
N2—Dy—O3—C10 133.1 (2) O8—Dy—C20—O7 179.6 (3)
C20—Dy—O3—C10 175.0 (2) N1—Dy—C20—O7 22.5 (2)
Dy i—Dy—O3—C10 −92.39 (18) N2—Dy—C20—O7 −39.90 (19)
O1—C2—C3—C4 177.7 (4) Dy i—Dy—C20—O7 172.8 (2)
C7—C2—C3—C4 −1.5 (6) O8 i—Dy—C20—O8 −10.1 (2)
O8 i—Dy—O4—C10 100.86 (19) O12 i—Dy—C20—O8 63.97 (17)
O12 i—Dy—O4—C10 39.8 (2) O11—Dy—C20—O8 −81.97 (17)
O11—Dy—O4—C10 179.28 (19) O3—Dy—C20—O8 99.8 (3)
O3—Dy—O4—C10 0.83 (17) O4—Dy—C20—O8 −86.8 (2)
O7—Dy—O4—C10 −131.87 (19) O7—Dy—C20—O8 −179.6 (3)
O8—Dy—O4—C10 141.16 (18) N1—Dy—C20—O8 −157.13 (17)
N1—Dy—O4—C10 −97.76 (19) N2—Dy—C20—O8 140.51 (17)
N2—Dy—O4—C10 −49.4 (2) Dy i—Dy—C20—O8 −6.79 (14)
C20—Dy—O4—C10 −175.94 (18) C21—O9—C22—C27 −177.9 (4)
Dy i—Dy—O4—C10 117.75 (17) C21—O9—C22—C23 0.8 (6)
C2—C3—C4—C5 0.6 (6) O9—C22—C23—C24 −179.5 (4)
C3—C4—C5—C6 0.7 (6) C27—C22—C23—C24 −0.8 (6)
C3—C4—C5—C9 178.8 (3) C22—C23—C24—C25 −0.1 (6)
C4—C5—C6—C7 −1.0 (5) C23—C24—C25—C26 1.0 (5)
C9—C5—C6—C7 −179.1 (3) C23—C24—C25—C29 −179.9 (3)
O8 i—Dy—O7—C20 −12.6 (2) C24—C25—C26—C27 −1.0 (5)
O12 i—Dy—O7—C20 62.65 (19) C29—C25—C26—C27 180.0 (3)
O11—Dy—O7—C20 −75.93 (19) O9—C22—C27—O10 −0.5 (5)
O3—Dy—O7—C20 139.31 (19) C23—C22—C27—O10 −179.3 (4)
O4—Dy—O7—C20 −124.29 (19) O9—C22—C27—C26 179.7 (3)
O8—Dy—O7—C20 −0.23 (17) C23—C22—C27—C26 0.9 (6)
N1—Dy—O7—C20 −157.3 (2) C28—O10—C27—C22 173.1 (4)
N2—Dy—O7—C20 135.8 (2) C28—O10—C27—C26 −7.1 (6)
C10—Dy—O7—C20 −171.0 (2) C25—C26—C27—C22 0.0 (6)
Dy i—Dy—O7—C20 −6.31 (18) C25—C26—C27—O10 −179.8 (4)
C8—O2—C7—C6 −9.5 (6) C26—C25—C29—C30 −131.6 (3)
C8—O2—C7—C2 172.6 (4) C24—C25—C29—C30 49.3 (4)
C5—C6—C7—O2 −177.7 (3) Dy—O11—C30—O12 −24.2 (5)
C5—C6—C7—C2 0.1 (5) Dy—O11—C30—C29 154.3 (2)
C3—C2—C7—O2 179.2 (3) Dy i—O12—C30—O11 10.4 (6)
O1—C2—C7—O2 −0.1 (5) Dy i—O12—C30—C29 −168.1 (2)
C3—C2—C7—C6 1.2 (6) C25—C29—C30—O11 −104.8 (3)
O1—C2—C7—C6 −178.1 (3) C25—C29—C30—O12 73.9 (4)
O8 i—Dy—O8—C20 169.6 (2) C42—N1—C31—C32 0.4 (5)
O12 i—Dy—O8—C20 −110.19 (18) Dy—N1—C31—C32 −172.8 (3)
O11—Dy—O8—C20 89.53 (18) N1—C31—C32—C33 1.6 (6)
O3—Dy—O8—C20 −131.90 (19) C31—C32—C33—C34 −1.7 (6)
O4—Dy—O8—C20 128.75 (17) C32—C33—C34—C42 0.1 (6)
O7—Dy—O8—C20 0.23 (16) C32—C33—C34—C35 178.2 (4)
N1—Dy—O8—C20 27.6 (2) C33—C34—C35—C36 177.8 (4)
N2—Dy—O8—C20 −41.22 (18) C42—C34—C35—C36 −4.1 (6)
C10—Dy—O8—C20 170.3 (2) C34—C35—C36—C37 −0.1 (7)
Dy i—Dy—O8—C20 169.6 (2) C35—C36—C37—C38 −177.8 (4)
O8 i—Dy—O8—Dy i 0.0 C35—C36—C37—C41 3.4 (6)
O12 i—Dy—O8—Dy i 80.24 (9) C41—C37—C38—C39 0.7 (5)
O11—Dy—O8—Dy i −80.05 (9) C36—C37—C38—C39 −178.1 (4)
O3—Dy—O8—Dy i 58.52 (16) C37—C38—C39—C40 0.4 (6)
O4—Dy—O8—Dy i −40.83 (14) C41—N2—C40—C39 0.9 (5)
O7—Dy—O8—Dy i −169.35 (13) Dy—N2—C40—C39 169.9 (3)
N1—Dy—O8—Dy i −142.00 (9) C38—C39—C40—N2 −1.3 (6)
N2—Dy—O8—Dy i 149.20 (9) C40—N2—C41—C37 0.3 (5)
C10—Dy—O8—Dy i 0.7 (2) Dy—N2—C41—C37 −169.4 (2)
C20—Dy—O8—Dy i −169.6 (2) C40—N2—C41—C42 −179.5 (3)
C6—C5—C9—C10 104.3 (4) Dy—N2—C41—C42 10.8 (4)
C4—C5—C9—C10 −73.8 (5) C38—C37—C41—N2 −1.1 (5)
Dy—O4—C10—O3 −1.5 (3) C36—C37—C41—N2 177.8 (3)
Dy—O4—C10—C9 178.9 (3) C38—C37—C41—C42 178.7 (3)
Dy—O3—C10—O4 1.5 (3) C36—C37—C41—C42 −2.4 (5)
Dy—O3—C10—C9 −178.8 (3) C31—N1—C42—C34 −2.2 (5)
C5—C9—C10—O4 8.8 (5) Dy—N1—C42—C34 171.0 (2)
C5—C9—C10—O3 −170.9 (3) C31—N1—C42—C41 176.6 (3)
O8 i—Dy—C10—O4 −73.80 (18) Dy—N1—C42—C41 −10.1 (4)
O12 i—Dy—C10—O4 −147.15 (17) C33—C34—C42—N1 2.0 (5)
O11—Dy—C10—O4 −0.71 (19) C35—C34—C42—N1 −176.3 (3)
O3—Dy—C10—O4 −178.5 (3) C33—C34—C42—C41 −176.8 (3)
O7—Dy—C10—O4 88.3 (3) C35—C34—C42—C41 4.9 (5)
O8—Dy—C10—O4 −74.5 (3) N2—C41—C42—N1 −0.8 (4)
N1—Dy—C10—O4 74.55 (18) C37—C41—C42—N1 179.4 (3)
N2—Dy—C10—O4 135.87 (18) N2—C41—C42—C34 178.1 (3)
Dy i—Dy—C10—O4 −74.02 (19) C37—C41—C42—C34 −1.7 (5)

Symmetry codes: (i) − x, − y+1, − z+1.

Hydrogen-bond geometry (Å, °)

D—H··· A D—H H··· A D··· A D—H··· A
C1—H1A···O6 ii 0.96 2.54 3.320 (5) 138
C16—H16A···O3 iii 0.93 2.53 3.425 (4) 161
C18—H18B···O3 iii 0.96 2.36 3.262 (4) 156
C21—H21A···O1 iv 0.96 2.49 3.362 (6) 151
C21—H21A···O2 iv 0.96 2.43 3.214 (5) 139
C33—H33A···O7 v 0.93 2.38 3.231 (4) 153
C31—H31A···O4 0.93 2.52 2.977 (4) 111

Symmetry codes: (ii) x, y+1, z−1; (iii) x, y−1, z; (iv) − x, − y+2, − z; (v) − x+1, − y+1, − z+1.

References

1  

Bruker (2006). APEX2 and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.

2  

Li, X., Zhang, T.-T., Ju, Y.-L., Wang, C.-Y., Li, Y.-Q., Zhang, L. & Zhang, Q. (2007). J. Coord. Chem. 60, 2121–2132.

3  

Li, X., Zhang, Z.-Y. & Song, H.-B. (2006). J. Chem. Crystallogr. 36, 99–103.

4  

Sheldrick, G. M. (1996). SADABS University of Göttingen, Germany.

5  

Sheldrick, G. M. (2008). Acta Cryst. A 64, 112–122.

Figures and Tables

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯ A D—H H⋯ A DA D—H⋯ A
C1—H1 A⋯O6 i 0.96 2.54 3.320 (5) 138
C16—H16 A⋯O3 ii 0.93 2.53 3.425 (4) 161
C18—H18 B⋯O3 ii 0.96 2.36 3.262 (4) 156
C21—H21 A⋯O1 iii 0.96 2.49 3.362 (6) 151
C21—H21 A⋯O2 iii 0.96 2.43 3.214 (5) 139
C33—H33 A⋯O7 iv 0.93 2.38 3.231 (4) 153
C31—H31 A⋯O4 0.93 2.52 2.977 (4) 111

Symmetry codes: (i) e-66-0m291-efi2.jpg ; (ii) e-66-0m291-efi3.jpg ; (iii) e-66-0m291-efi4.jpg ; (iv) e-66-0m291-efi5.jpg .